快速城镇化进程中珠江三角洲高铵地下水赋存环境及驱动因素          下载免费PDF全文

吕晓立  刘景涛  韩占涛  朱亮  杨明楠  李海军 《中国地质》2021,48(6):1770-1780

地下水中高浓度的铵态氮对生活饮用水安全及生态环境存在潜在威胁。相比较硝态氮，高浓度的铵态氮不仅有各种人为来源，天然沉积环境更是造成高铵地下水的主要成因。本文以城镇化快速发展的珠江三角洲为研究区，运用数理统计、主成分分析等方法深入探讨了研究区高铵地下水的赋存环境特征及驱动因素。结果表明，研究区地下水中NH₄⁺质量浓度介于未检出~180 mg/L。研究区1539组地下水样品中，NH₄⁺质量浓度大于10 mg/L的高铵地下水69组，其中含NH₄⁺质量浓度大于30 mg/L的高铵"肥水"23组。对比2005-2008年历史水化学数据，2009-2018年新增建设用地孔隙含水层高铵地下水样品比例增加25%。高铵地下水呈斑块状分布于三角洲平原区第四系底部低洼的基底、洼地等退积层序发育的淤泥质含水层中。淤泥层等富含有机质和总有机碳的沉积层是珠江三角洲地区的"生铵层"，有机氮的矿化是三角洲平原区城市化孔隙含水层中高铵地下水的主要驱动力。城镇化扩张引起生活污水及富铵工业废水的泄漏入渗是城乡结合部高铵地下水铵氮的重要来源。三角洲平原区中性至弱碱性富含有机质的还原环境是高铵地下水的主要成因。风化溶滤、阳离子交换吸附、海陆交互作用是珠江三角洲高铵地下水质演变的主要水文地球化学过程。  相似文献   

Particulate content of savanna fire emissions   总被引：9，自引：0，他引：9  

Hélène Cachier  Catherine Liousse  Patrick Buat-Menard  Annie Gaudichet 《Journal of Atmospheric Chemistry》1995,22(1-2):123-148

As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO₂ real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO₂) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg C_{dry plant} and EF(Ct)=7.4±3.4 and 56±16 g C/kg C_{dry plant} for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions.  相似文献   

Micro-spectroscopic investigations of highly heterogeneous waste repository materials   总被引：1，自引：0，他引：1  

A.M. Scheidegger  D. Grolimund  C.R. Cheeseman  R.D. Rogers 《Journal of Geochemical Exploration》2006,88(1-3):59

Assuring safe disposal and long-term storage of radioactive and toxic wastes corresponds to a primary environmental task of present societies. To improve any technical limitation, a mechanistic understanding of the processes governing the binding of heavy metals and radionuclides is required. In this study, the significance of synchrotron-based X-ray microprobes for elucidating the spatial distribution and the speciation of radionuclides in highly heterogeneous waste repository materials will be outlined. A case study on the uptake process of Co in cementitious engineered barrier materials exposed to microbial degradation will be presented.  相似文献   

均匀设计在室内大型注浆试验研究中的应用          下载免费PDF全文

杨坪  陈安 《探矿工程》2006,33(3):9-11

介绍了均匀设计试验方法的特点及优越性，利用试验点在试验范围内的均匀分布，能大大减少试验次数且获得较好的试验效果。将均匀设计方法引入到注浆试验研究中，并对试验进行了详细设计，实践表明，均匀设计试验法是一种有效、可靠的试验设计方法。  相似文献   

基于遥感的民勤绿洲植被覆盖变化定量监测   总被引：16，自引：0，他引：16  

高志海  李增元  魏怀东  丁锋 《地理研究》2006,25(4):587-595

基于混合像元条件下的TM影像植被覆盖度遥感反演,定量研究了甘肃省民勤绿洲1987年至2001年植被覆盖时空变化的规律与特点。结果表明,15年中,民勤绿洲的植被覆盖发生了很大的变化,农田植被(耕地)面积增加了53.11%,而中、高盖度植被的面积却减少了25.21%,这对民勤绿洲的长久生态安全构成了严重的威胁。民勤绿洲植被覆盖变化的空间转化过程复杂,但总体属于开垦—植被退化型。15年中因开垦和植被退化而损失的中、高盖度植被达42204.81hm2,占原面积的81.73%,而且损失的主要是绿洲边缘的防风固沙植被,其中因开垦损失的面积为18776.08hm2,占损失面积的44.5%。超采地下水引起的地下水位快速下降是导致绿洲边缘天然和人工灌丛植被退化的主要原因。控制开垦并培育相对稳定的灌丛型植被,应该是研究区生态环境建设的重点。  相似文献   

流动人口分布与区域经济发展关系若干解释(1990、2000)   总被引：10，自引：1，他引：10  

鲁奇  王国霞  杨春悦  曾磊 《地理研究》2006,25(5):765-774

本文对我国1990、2000年间流动人口在东、中、西部和东部地区中环渤海、长江三角洲、珠江三角洲及福建三个亚区的分布变化以及这一分布变化与上述各地区各相关经济与非经济因素变化的关系进行了研究。研究发现,10年中流动人口东、中、西部分布变化与东、中、西部经济发展的变化高度一致;而10年中流动人口在东部地区环渤海、长江三角洲、珠江三角洲及福建这三个亚区层面的分布变化则与经济发展要素变化有一致的方面,也有不一致的方面。珠江三角洲及福建的经济增长带来了流动人口的大幅增长,除珠江三角洲劳动密集型企业众多外,这可能与该区域地方社会人文等文化本底所决定的经济发展制度及习俗有一定的相关性。  相似文献   

基于重庆主城区居民感知的城市意象元素分析评价   总被引：14，自引：2，他引：14  

冯维波  黄光宇 《地理研究》2006,25(5):803-813

城市意象是诠释一个城市环境的重要指标,对其分析研究,有助于解读及评估城市景观的优劣、城市生活环境品质的高低,也有助于把握城市空间结构。本文首先在回顾国内外相关研究进展的基础上,根据重庆城市特色,将Lynch K的5类城市意象要素进行细分,并转换为地点场所意象元素;其次采用问卷调查法,对城市意象因子和意象元素分别进行评价,并绘制城市意象元素分布图,以了解居民对城市意象元素的印象与品质之间的关系,从而为重庆城市规划建设提供有益的参考。  相似文献   

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China   总被引：7，自引：0，他引：7  

Pingjiu Zhang  Lianqing Li  Genxing Pan  Jingchen Ren 《Environmental Geology》2006,51(4):609-619

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.  相似文献   

黄河源地区草地退化空间特征   总被引：54，自引：4，他引：54  

张镱锂  刘林山  摆万奇  沈振西  阎建忠  丁明军  李双成  郑度 《地理学报》2006,61(1):3-14

利用黄河源地区1985年和2000年1：100000土地利用／覆被数据，结合1：250000DEM、道路和居民点数据与野外调查资料，分析草地退化与坡向、海拔及距道路和居民点距离之间的关系．探讨黄河源区15年间土地覆被变化特征与规律。结果表明，退化草地占源区总面积的8．24％，冬春季牧场退化率显著高于夏季牧场：草地退化是黄河源区研究时段内土地利用／覆被变化最主要的特征。草地退化表现为：①阳坡退化率高于阴坡；②受人口密度影响，草地退化率与海拔高度成反比，相关系数为．0．925；③距离居民点越近。退化率越高。尤其当与居民点距离≤12km时，草地退化率与其相关系数高达-0．996；④在距道路4km以内．草地退化率与道路距离成反比．相关系数高达-0．978。1985年以来，源区的草地退化有自然因素的影响．但人类活动的影响仍起主导作用。科学地减少当地居民对草地的过分依赖是解决脆弱的江河源区环境退化的根本。  相似文献   

大渡河上游不同地带居民对环境退化的响应   总被引：6，自引：2，他引：6  

阎建忠  张镱锂  朱会义  摆万奇  郑度 《地理学报》2006,61(2):146-156

青藏高原的环境退化引起了极大的关注,但农牧民如何认识和响应环境退化,还缺乏实证研究.采用参与性农村评估法,对大渡河上游不同地带典型村（位于河谷区的丹扎木村、中山区的克尔马村和山原区的日科村）的农牧民进行调查和对比分析.研究表明：①大渡河上游不同地带的居民对环境退化具有不同的响应过程.河谷区通过劳动力向二、三产业转移,缓解了人口压力,采取积极的措施来应对自然灾害和森林退化;中山区以劳动力向二、三产业转移和发展畜牧业来缓解人口压力,没有采取积极的措施应对环境退化：山原区的劳动力不能转移到二、三产业,只能通过增加牲畜数量来解决生计,牧民仅采取一些积极的措施来应对草料不足的问题和雪灾等自然灾害.在大渡河上游,最脆弱的区域是中山区和山原区,而不是人口压力大的河谷区.②生计方式是影响居民响应人口压力和环境退化的关键因素.基于居民的生计方式来解释和解决生态脆弱区的人口压力和环境退化问题,将是一个新的方向.③劳动力向二、三产业转移有利于居民改善生计.降低教育收费和进行基础设施建设,将加快劳动力向二、三产业转移.  相似文献